Concept information
Preferred term
hydrogen bond
Definition
- A hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative atom or group, and another electronegative atom bearing a lone pair of electrons-the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted Dn-H···Ac, where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms, and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent or ionic bonds. (From DBpedia)
Entry terms
- hydrogen bonding
Belongs to group
In other languages
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French
URI
http://data.loterre.fr/ark:/67375/37T-D1N0XRG9-D
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